Looking at the item description, it's most likely Sigurd.
Sigurd, also known as Siegfried, has a role in "Nibelungenlied", a german poem. In this poem, he bathes in a dragon's blood, and his skin becomes impervious to all attacks, except for a single point where a leaf adhered to his skin. According to TVTropes, there's a character named Siegfried in the anime Saint Seiya, that uses the same backstory.